It is very likely that you can do what you want without copying any characters and therefore without any chance of copyright infringement. Look at the first letter I in my answer. I entered "capital letter I", I didn't enter "one long vertical line with one shorter horizontal line both at the top and the bottom of the vertical line".
So if you wanted to distribute an iOS app that shows a giant smiley face, you would create a text field, add the code point for "Unicode smiley letter", change the font size to 500 pt or something similar big, and iOS will draw the smiley face for you, without you copying anything that is copyrighted. And if you want an Android app showing a giant smiley face, you would do the same thing.
Where you have a problem: If you want an Android app that shows a giant iOS smiley face. Because the iOS smiley and the Android smiley look quite similar, but not identical. To achieve this technically, you could make a screen shot on your iPhone, and copy the image with the iOS smiley face, and show it in your Android app. Now you have copied the actual image. And these images are copyrighted, and there is no conceivable fair use defense (because you could have just used the Android smiley without any copyright infringement). So if Apple cares, you would be in trouble for copyright infringement.
The image in a PDF file changes because you didn't paste an actual lightbulb image, you pasted the Unicode code point of an image, and every computer capable of showing it will display its own built-in lightbulb image. And they will be different.
If you print a book with emojis in it, you should check which license you actually have. It is quite possible that you have permission by the copyright holder to use the actual images when producing printed books. It heppens quite often that people send PDF files to their printer (I mean to the company that prints books for them). You'd have code points in your PDF files (nothing copied) and the printer may use a Mac or a PC to print the book, and get some different images in your book.